Functional and Antioxidant Properties of Plastic Bottle Caps Incorporated with BHA or BHT

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The use of a pacifier has been reported to be a causative factor of recurrent acute otitis media

(RAOM) because the negative pressure which is generated during sucking may cause a negative intra-tympanic pressure and favour the reflux of nasopharyngeal secretions into the Eustachian tube. Push and pull (P&P) plastic bottle caps, recently marketed in Italy, might also induce negative nasopharyngeal pressure.
  • This study was aimed to investigate if there is a difference in the prevalence of habitual use of P&P plastic bottle caps among children with a positive history of RAOM and healthy controls.
  • A telephonic interview was performed in order to retrospectively evaluate the prevalence of habitual use of P&P plastic bottle cap among children with a history of RAOM and healthy controls, comparable to the former for environmental risk factors for RAOM.
  • Data were obtained from 57 Caucasian patients (males=36/57; 63.2%) with a median age of 59 (range=21-90) months, including 28 children with a history of RAOM and 29 healthy controls.
  • Habitual use of P&P plastic bottle cap was significantly (p=0.047) more frequent in children with a history of RAOM (14/28; 50.0%) than in control group (7/29; 24.2%). Multivariate logistic regression analysis adjusted for age confirmed a significant association (p<0.01; Pseudo R(2)=0.2) between the use of P&P plastic bottle cap and a positive history of RAOM (adjusted OR=4.0; range=1.1-15.0).
  • Our preliminary data show a significantly increased prevalence of P&P plastic cap bottle habitual users among children with a history or RAOM and support the need for larger studies to confirm the role of using P&P bottles as risk factor of RAOM and to identify the age groups at higher risk.

We report a rare case of late knee locking after an open knee injury in a polytrauma patient with a pelvic fracture and a contralateral femoral artery injury.

  1. Once the life and limb threatening injuries were addressed, debridement and washout of the knee wound was performed. X-rays and subsequent CT revealed only an undisplaced patella fracture. The patient presented 6 months later to a knee surgeon with recurrent locking.
  2. An arthroscopy was performed and a 10 mm plastic soft drink bottle cap was retrieved leading to the immediate resolution of symptoms without complications. Open knee injuries require thorough debridement washout and joint assessment. Late locking should raise the suspicion of an intra-articular loose or foreign body. Arthroscopy is an excellent first line tool in the diagnosis and late management of this unusual problem.
  3. Reusable plastic sports bottles are used extensively worldwide, and little is known about the migration of chemicals from the bottles into drinking water. In this study, we investigated the chemical migration into drinking water stored for 24 h in new bottles, used bottles and bottles washed in the dishwasher.
  4. Non-target screening (NTS) by liquid-chromatography – high-resolution mass spectrometry (LC-HRMS) was performed to identify these compounds. We detected > 3500 dishwasher related compounds, with 430 showing migration even after subsequent flushing of the bottles.
  5. In addition, more than 400 plastic related compounds were detected, with high peaks for oligomers suspected to originate from the biodegradable polyester polycaprolactone, and aromatic amines, which may have been introduced as slip agents or antioxidants. These compounds have never been reported before in bottled water. Most of the identified compounds migrating out of the used bottles were plasticizers, antioxidants or photoinitiators.
  6. The presence of photoinitiators are of particular concern, due to possible endocrine disrupting effects. Furthermore, diethyltoluamide (DEET) was detected, which may have been formed from the plasticizer laurolactam. Typically, the dishwashing process enhanced the leaching of plastic related compounds, and even after additional water flushing, the average peak intensity of these compounds was only reduced by half.

Metal-organic frameworks (MOFs) derived from recycled polyester (polyethylene terephthalate, PET) bottles were investigated in both batch and column studies for the removal of arsenate.

As-synthesized Fe-MOF, Zr-MOF, and La-MOF were systematically analyzed by SEM, PXRD, FTIR, BET, and XPS techniques. The obtained MOFs showed high crystallinity with the specific surface area of 128.3, 290.4, and 61.8 m2/g for Fe-MOF, Zr-MOF, and La-MOF, respectively. The Langmuir isotherm and pseudo-second-order kinetic model simulated arsenate adsorption on MOF materials well, which can be explained by electrostatic interactions, surface complexation, and ligand exchange mechanisms.
The maximum adsorption capacities of arsenate onto Fe-MOF, Zr-MOF, and La-MOF were found to be 70.02, 85.72, and 114.23 mg/g at pH 7, respectively. The effect of pH and co-existing anions on the arsenate adsorption on MOF materials was also evaluated for practical applications. The MOF materials showed reduced adsorption capacity for arsenate by less than 10% up to four cycles of regeneration and did not induce any significant (p > 0.05) acute toxicity (<2.5% mortality) in Daphnia magna.

Flugs® - Plastic Fly Bottles

49-100 Genesee Scientific 1000 Flugs/Unit 149 EUR

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59-194P Genesee Scientific 2560 Plugs/Unit 670.75 EUR

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8396 Scientific Laboratory Supplies PK12 144.45 EUR

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8388 Scientific Laboratory Supplies PK24 126.9 EUR

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CD04-R50P PHOENIX PEPTIDE 50 ml 297 EUR

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152306 Scientific Laboratory Supplies PK10 171.45 EUR

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PW1277-1X100NO EWC Diagnostics 1 unit 113.69 EUR

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2107-0016 Scientific Laboratory Supplies PK16 441.45 EUR

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E5920717006 Scientific Laboratory Supplies EACH 359.1 EUR

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218064406 Scientific Laboratory Supplies PK10 548.1 EUR

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E5910751001 Scientific Laboratory Supplies PK2 504.9 EUR

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4oz Clear Bottles - PK80

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Rack For 9 Bottles 2000ml - EACH

WAS6164 Scientific Laboratory Supplies EACH 605.15 EUR

Rack For 16 Bottles 1000ml - EACH

WAS6166 Scientific Laboratory Supplies EACH 400.98 EUR

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240862 Scientific Laboratory Supplies PK10 157.16 EUR

Rack For 20 Bottles 500ml - EACH

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BOT0350 Scientific Laboratory Supplies PK12 214.65 EUR

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BOT0352 Scientific Laboratory Supplies PK12 224.1 EUR

Heat Extractor with Plastic Knob

IMS006 ScyTek Laboratories 1 ea. 164.4 EUR

Sample Bottles Undosed Sterile Green Cap 1000ml - PK56

WAT5624 Scientific Laboratory Supplies PK56 124.2 EUR

50 ml Tube Storage Boxes, Plastic

B619 ABM 5/pack 62.5 EUR

Nalgene Square Media Bottles PETG with HDPE closures in shrink wrapped trays. sterile. - PK280

342020-0030 Scientific Laboratory Supplies PK280 1013.85 EUR

Bottles Powder Clear 250ml - PK42

BP250C Scientific Laboratory Supplies PK42 27 EUR

Powder Bottles 30ml Clear - PK80

BP30C80 Scientific Laboratory Supplies PK80 33.75 EUR

Sample Bottles Undosed Sterile Green Cap 500ml - PK84

WAT5614 Scientific Laboratory Supplies PK84 148.35 EUR

Pack of 2 suction bottles 100ml - PK2

WAT4874 Scientific Laboratory Supplies PK2 565.49 EUR

Honey Jar 375ml with Plastic Cap Sterile - PK100

CON7774 Scientific Laboratory Supplies PK100 108 EUR

Biological Stain Kit, 5 Bottles

43320000-1 Glycomatrix 1 PK(s) 76.53 EUR

Reagent Bottles Amber 500ml - PK10

BOT53080A Scientific Laboratory Supplies PK10 402.3 EUR

Droso-filler For Bottles - EACH

FLY1282 Scientific Laboratory Supplies EACH 11054.19 EUR

Sample Bottles Undosed Sterile Green Cap 250ml - PK140

WAT5604 Scientific Laboratory Supplies PK140 173.32 EUR

Sample Bottles Non Sterile Undosed Red Cap 1000ml - PK56

WAT5626 Scientific Laboratory Supplies PK56 83.72 EUR

60ml HDPE Nalgene Bottles - PK1000

3121890002 Scientific Laboratory Supplies PK1000 1417.5 EUR

500 ml Glass Bottle with cap

B603 ABM Set of 5 62.5 EUR

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2203-0010 Scientific Laboratory Supplies PK6 278.1 EUR

Rack For 48 Bottles 50ml - EACH

WAS6174 Scientific Laboratory Supplies EACH 656.55 EUR

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WAT5622 Scientific Laboratory Supplies PK56 105.75 EUR

250ml Adaptors Conical Bottles - PK2

E5825741005 Scientific Laboratory Supplies PK2 333.45 EUR

Bottles Sod Thio Dosed 18mg/L St. Blue Cap 1000ml - PK56

WAT5620 Scientific Laboratory Supplies PK56 105.75 EUR

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WAT5621 Scientific Laboratory Supplies PK56 105.75 EUR

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WAT5616 Scientific Laboratory Supplies PK84 110.16 EUR

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BOT8940 Scientific Laboratory Supplies EACH 116.1 EUR

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WAT5612 Scientific Laboratory Supplies PK84 141 EUR

Tube Culture With Svl Plastic - PK40

B99485 Scientific Laboratory Supplies PK40 498.15 EUR

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PLA005-1NO EWC Diagnostics 1 unit 816.58 EUR

Bottles Sod Thio Dosed 18mg/L St. Blue Cap 500ml - PK84

WAT5610 Scientific Laboratory Supplies PK84 154.22 EUR

Bottles Sod Thio Dosed 180mg/L St. Blue Cap 500ml - PK84

WAT5611 Scientific Laboratory Supplies PK84 141 EUR

Sample Bottles EDTA Dosed Sterile White Cap 250ml - PK140

WAT5602 Scientific Laboratory Supplies PK140 183.6 EUR

South American FBS Serum 500ml Bottles - 500ML

35-079-CV Scientific Laboratory Supplies 500ML 472.5 EUR

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ARG1300 Scientific Laboratory Supplies EACH 69.47 EUR

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322002-9025 Scientific Laboratory Supplies PK1500 2134.35 EUR

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BottleS Sod. Thio Dosed 18mg/L St. Blue Cap 250ml - PK140

WAT5600 Scientific Laboratory Supplies PK140 248.4 EUR

Bottles Sod. Thio Dosed 180mg/L St. Blue Cap 250ml - PK140

WAT5601 Scientific Laboratory Supplies PK140 240.88 EUR

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BOT0354 Scientific Laboratory Supplies PK24 265.95 EUR

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X24085 Scientific Laboratory Supplies EACH 175.5 EUR

Flystuff (59-194) Droso-Plugs Cap for Bottles - PK1536

FLY1202 Scientific Laboratory Supplies PK1536 1007.6 EUR

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2004-9025 Scientific Laboratory Supplies PK12 24.3 EUR

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2070POUR Scientific Laboratory Supplies PK10 12.15 EUR

HDPE Bottles Narrow Mouth 30mL - PK1000

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312002-0002 Scientific Laboratory Supplies PK1000 1263.6 EUR

8-strip Plastic Comb, Compatible with 503711&503761, Sterile, 2/pk, 50/box, 500/

509261 NEST Biotechnology 500 pcs/cs 147.4 EUR

Nalgene Rectangular Amber HDPE Bottles 500ml - PK48

2009-0016 Scientific Laboratory Supplies PK48 384.75 EUR

Wide mouth wash bottles safety labeled

Z423106-1PAK Scientific Laboratory Supplies PK6 49.68 EUR

Wide mouth wash bottles safety labeled

Z423122-1PAK Scientific Laboratory Supplies PK6 63.63 EUR

Wide mouth wash bottles safety labeled

Z423149-1PAK Scientific Laboratory Supplies PK6 49.68 EUR

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Z423335-1PAK Scientific Laboratory Supplies PK6 63.63 EUR

8-strip Plastic Comb, Compatible with 503711&503761, Non-Sterile, 2/pk, 50/box,

509211 NEST Biotechnology 500 pcs/cs 137.94 EUR

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LHD-V5P PHOENIX PEPTIDE 5-50ml 435 EUR

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L.J. Medium Slant in thick glass bottles

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L.J. Medium Slant in thick glass bottles

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Gallium Pieces, 99.9999%

GX1351 Glentham Life Sciences 10g 957.72 EUR

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GX4649 Glentham Life Sciences 50g 503.32 EUR

Gallium Pieces, 99.99999%

GX9105 Glentham Life Sciences 10g 1122.53 EUR

Gallium Pieces, 99.9999%

GX1351-10 Glentham Life Sciences 10 171 EUR

Gallium Pieces, 99.9999%

GX1351-100 Glentham Life Sciences 100 801.6 EUR

Gallium Pieces, 99.9999%

GX1351-50 Glentham Life Sciences 50 498.5 EUR

Bismuth Pieces, 99.9999%

GX4649-250 Glentham Life Sciences 250 436.6 EUR

Bismuth Pieces, 99.9999%

GX4649-50 Glentham Life Sciences 50 177.5 EUR

Gallium Pieces, 99.99999%

GX9105-10 Glentham Life Sciences 10 198.7 EUR

Gallium Pieces, 99.99999%

GX9105-100 Glentham Life Sciences 100 935.2 EUR

Gallium Pieces, 99.99999%

GX9105-50 Glentham Life Sciences 50 614.3 EUR

DURAN(R) PRESSURE PLUS BOTTLES VOLUME - PK10

Z742281-10EA Scientific Laboratory Supplies PK10 274.05 EUR

Wide mouth wash bottles safety labeled - PK6

Z423092-1PAK Scientific Laboratory Supplies PK6 76.95 EUR

Antimony Pieces, 99.9999%

GX8733 Glentham Life Sciences 25g 893.63 EUR

Antimony Pieces, 99.9999%

GX8733-25 Glentham Life Sciences 25 180.9 EUR

Antimony Pieces, 99.9999%

GX8733-250 Glentham Life Sciences 250 751 EUR

Antimony Pieces, 99.9999%

GX8733-50 Glentham Life Sciences 50 283.5 EUR

Duran Stirred Reactor for 250mL Bottles - EACH

BOT1138 Scientific Laboratory Supplies EACH 413.1 EUR

Water Sampling Bottles HDPE 500ml Dosed - PK100

WAT5512 Scientific Laboratory Supplies PK100 292.95 EUR

Indium Pieces, 99.999%

GX0999 Glentham Life Sciences 25g 548.4 EUR

Indium Pieces, 99.999%

GX0999-100 Glentham Life Sciences 100 474.2 EUR

Indium Pieces, 99.999%

GX0999-25 Glentham Life Sciences 25 192.2 EUR

ELISA Microplate Washer Automated (#MPW-30) bottle set (3 bottles and cap assembly)

MPW-30-SET Alpha Diagnostics 1 489.6 EUR

Support stand with plastic convertor clamp - EACH

HOM2662 Scientific Laboratory Supplies EACH 477.36 EUR

Bismuth Pieces, 99.999%

GX2132 Glentham Life Sciences 50g 362.93 EUR

Bismuth Pieces, 99.999%

GX2132-1 Glentham Life Sciences 1 324.4 EUR

Bismuth Pieces, 99.999%

GX2132-250 Glentham Life Sciences 250 138.6 EUR

Bismuth Pieces, 99.999%

GX2132-50 Glentham Life Sciences 50 104 EUR

Plastic tuberculine syringe with drain tube - EACH

WAT4836 Scientific Laboratory Supplies EACH 211.51 EUR

Antimony Pieces, 99.999%

GX7845 Glentham Life Sciences 25g 1472.9 EUR

Antimony Pieces, 99.999%

GX7845-100 Glentham Life Sciences 100 340.5 EUR

Antimony Pieces, 99.999%

GX7845-25 Glentham Life Sciences 25 134.1 EUR

Antimony Pieces, 99.999%

GX7845-500 Glentham Life Sciences 500 1218.8 EUR

Water Sampling Bottles HDPE 250ml Undosed - PK312

WAT5500 Scientific Laboratory Supplies PK312 594 EUR

Water Sampling Bottles HDPE 500ml Undosed - PK100

WAT5510 Scientific Laboratory Supplies PK100 221.4 EUR

Gallium Pieces,

GX4776 Glentham Life Sciences 10g 838.08 EUR

Gallium Pieces,

GX4776-10 Glentham Life Sciences 10 131.1 EUR

Gallium Pieces,

GX4776-100 Glentham Life Sciences 100 707.1 EUR

Gallium Pieces,

GX4776-50 Glentham Life Sciences 50 409 EUR

Plastic syringe 30ml with tube and clip - EACH

WAT4838 Scientific Laboratory Supplies EACH 211.51 EUR

Germanium Pieces max. 2 cm (50 Ohm cm); 99.9999+%

GX2202 Glentham Life Sciences 10g 1160.72 EUR

South American FBS Serum Heat Inactivated 500ml Bottles - 500ML

35-089-CV Scientific Laboratory Supplies 500ML 483.3 EUR

50 mL Serological Pipette, Individually Plastic-plastic Warpped, Sterile, 100/pk

329003 NEST Biotechnology 600 pcs/cs 194.37 EUR

DeepWell Plate (96 square well, 2.0 ml), 115 pieces

IN845-FX-8500115 Westburg each 583.15 EUR

250 mL Polystyrene Storage Bottles, Neck Size 45 mm, Sterile, 1/pk, 24/cs

342021 NEST Biotechnology 24 pcs/cs 36.3 EUR

500 mL Polystyrene Storage Bottles, Neck Size 45 mm, Sterile, 1/pk, 24/cs

343021 NEST Biotechnology 24 pcs/cs 41.8 EUR

150 mL Polystyrene Storage Bottles, Neck Size 45 mm, Sterile, 1/pk, 24/cs

346021 NEST Biotechnology 24 pcs/cs 32.34 EUR

Water Sampling Bottles HDPE 250ml Dosed Water Sampling Bottle - PK312

WAT5502 Scientific Laboratory Supplies PK312 792.45 EUR

Plungers for the supply/waste bottles x 2 - PK2

WAT4844 Scientific Laboratory Supplies PK2 553.74 EUR

Strontium Pieces max. 20 mm, under argon, coated with oil, Ba max. 1%, 99%

GX0588 Glentham Life Sciences 100g 713.3 EUR

Strontium Pieces max. 20 mm, under argon, coated with oil, Ba max. 1%, 99%

GX0588-100 Glentham Life Sciences 100 550.7 EUR

DeepWell Plate (96 square well, 2.0 ml), 25 pieces

IN845-FX-8500025 Westburg each 158.05 EUR

Square bottle 500 mL sterile with septum cap Nalgene - PK40

DD29554 Scientific Laboratory Supplies PK40 553.5 EUR

Multi-Level, 2 bottles each level (Low, Normal, High)

QCHGB RNA Medical each 121 EUR
In a flow-through system, Fe-MOF, Zr-MOF, and La-MOF were used to treat 176, 255, and 398 mL bed volumes of arsenate contaminated water, respectively, and consistently reduced the concentration of arsenate ions from 500 to 10 μg/L. This study clearly demonstrated that MOF materials derived from waste PET bottles are economically promising adsorbents for the successful elimination of arsenate species from aqueous environments.

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